![Org Lett](/sites/default/files/styles/original_ratio_zero/public/2021-07/orlef7_v018i016.jpg?itok=QHj0HtrD)
The rapid and efficient construction of complex chiral bicyclic amines is possible using a novel alkene diamination reaction. Electrophilic iodinating agents promote the intramolecular anti-selective diamination of alkenes and allow the efficient synthesis of chiral amines such as trans-bipyrrolidines.